@PHDTHESIS{Sal2008a,
author = {Stephen Salomons},
title = {Kinetic Models for a Diesel Oxidation Catalyst},
school = {University of Alberta},
year = {2008},
type = {{Ph.D.} Thesis},
month = {November},
abstract = {Automotive-based exhaust is a major contributor to air pollution,
and legislation controls the emission of several components. Catalytic
converters are used to reduce these emissions to acceptable levels.
As legislation becomes more stringent, better catalysts are required,
and better kinetic models can accelerate the design of these models.
This work considers the kinetics of the oxidation of CO and hydrogen
on a Pt monolith diesel oxidation catalyst under lean conditions.
The study of CO oxidation alone, while well documented in the literature,
is a necessary step in the development of a complete model. CO oxidation
is studied using both temperature ramp and concentration step experiments.
These experiments are modelled and discussed.
The selectivity of the catalyst toward CO is observed during light-off
experiments of CO and hydrogen mixtures. Literature models are modified
to correctly model this selectivity, improving the validity of the
modified model.
The hydrogen-promotion effect, whereby the presence of hydrogen promotes
CO oxidation during light-off, is discussed and modelled. Experimental
and numerical results are shown and compared, and modifications to
the standard literature models are proposed. These modifications
model the behaviour of the catalyst for mixtures of CO (up to 2000
ppm), hydrogen (up to 2000 ppm) and oxygen (6%), including the catalyst
selectivity and the hydrogen promotion effect.},
url = {http://catalysis.salomons.cc/Salomons2007-PhD-Kinetic_Models_for_a_Diesel_Oxidation_Catalyst.pdf}
}
@MASTERSTHESIS{Salomons2003,
author = {Stephen John Salomons},
title = {Modelling the behaviour of a reverse-flow catalytic reactor for the
combustion of lean methane},
school = {University of Alberta},
year = {2003},
type = {{M.Sc.} Thesis},
month = {January},
abstract = {Emissions of methane to the atmosphere are deemed by many to pose
environmental problems. {C}onversion of methane to carbon dioxide
through combustion reduces greenhouse gasses and can provide a source
of energy. {C}atalytic combustion is a viable option for oxidation
of lean methane streams. {L}ean methane mixtures can be very difficult
to oxidize due to the relative stability of methane, and high temperatures
are usually required. {O}ne option for increasing reactor temperature
is to use flow reversal to trap energy in the reactor. {T}his thesis
details the development, validation and use of a transient 2{D} model
for a reverse flow catalytic reactor. {I}t is demonstrated that a
2{D} model can show many dynamics in the system that cannot be accurately
reproduced with a 1{D} model. {T}he model is verified with experimental
data using a pilot scale reactor. {T}his research presents results
from numerical simulations and experiments into the effects of operating
parameters such as feed rate, methane concentration, and cycle time.},
comment = {\url{http://www.ualberta.ca/~salomons/CFRR-committee.pdf} Canadiana:
20042099447 AMICUS No. 29965876 \url{http://amicus.collectionscanada.ca/s4-bin/Main/ItemDisplay?l=0\&l_ef_l=-1\&id=242369.1331129\&v=1\&lvl=1\&coll=18\&rt=1\&rsn=S_WWWulafrZEJj\&all=1\&dt=NW+|}},
isbn = {0612823415},
language = {English},
owner = {Stephen},
url = {http://catalysis.salomons.cc/Salomons2003-MSc-Modelling_the_Behaviour_of_a_Reverse_Flow_Catalytic_Reactor.pdf}
}
@ARTICLE{Sal2009,
author = {S. Salomons and R.E. Hayes and M. Votsmeier},
title = {The promotion of carbon monoxide oxidation by hydrogen on supported
platinum catalyst},
journal = {Applied Catalysis A: General},
year = {2009},
volume = {352},
pages = {27-34},
number = {1-2},
abstract = {This paper reports the results of a study of the combined oxidation
of hydrogen and carbon monoxide on a platinum diesel oxidation catalyst.
Experimental results for the light-off curves obtained in a monolith
supported catalyst are shown for different concentrations. The presence
of hydrogen is shown to promote the oxidation of CO, with the largest
effect shown for the first small addition of hydrogen, then a progressively
decreasing effect as the hydrogen concentration is increased. The
enhancement effect can be successfully simulated using a kinetic
model in which the activation energy for the desorption of CO is
decreased as a function of hydrogen adsorption. Hydrogen is allowed
to adsorb on sites only accessible to hydrogen and not CO or oxygen.},
doi = {10.1016/j.apcata.2008.09.025},
keywords = {Platinum catalyst; Monolith; Carbon monoxide; Oxidation; Hydrogen
promotion; Simulation}
}
@ARTICLE{Sal2007,
author = {S. Salomons and R.E. Hayes and M. Votsmeier and A. Drochner and H.
Vogel and S. Malmberg and J. Gieshof},
title = {On the use of mechanistic {CO} oxidation models with a platinum monolith
catalyst},
journal = {Applied {C}atalysis {B}: {E}nvironmental},
year = {2007},
volume = {70},
pages = {305-313},
number = {1-4},
note = {\doi{10.1016/j.apcatb.2006.01.022}},
abstract = {This paper presents experiments and model predictions for the oxidation
of {CO} over a platinum catalyst in a monolith reactor. {E}xperimental
behaviour is broadly consistent with previously reported work on
{CO} oxidation. {I}gnition-extinction (light-off) curves demonstrated
the presence of multiple steady states with a hysteresis effect.
{T}he two branches corresponding to the two states of predominantly
{CO} covered or oxygen covered. {A}dmission of {CO} pulses to an
oxygen covered surface results in reaction, indicating the occurrence
of adsorption of {CO} on an oxygen covered surface. {A} model based
on adsorption and surface reaction using the classical {LHHW} approach
qualitatively was able to reproduce the light-off behaviour. {T}he
best model assumes dissociative chemisorption of oxygen on two surface
sites. {I}t was superior to a model proposing molecular adsorption
of oxygen followed by rapid dissociation. {A}ddition of steps allowing
{CO} adsorption on an oxygen filled surface via an “oxygen compression”
mechanism enable the qualitative description of the reactor response
to step inputs of {CO} to an oxygen rich feed stream. {S}ome parameter
adjustment remains to allow a better fit between experiment and model
predictions.},
doi = {10.1016/j.apcatb.2006.01.022}
}
@ARTICLE{Sal2006a,
author = {Stephen Salomons and Martin Votsmeier and R.E. Hayes and Alfons Drochner
and Herbert Vogel and Jürgen Gieshoff},
title = {C{O}+{{H}$_{2}$} {O}xidation on a {{P}t} based {M}onolith {D}iesel
{O}xidation {C}atalyst},
journal = {Catalysis {T}oday},
year = {2006},
volume = {117},
pages = {491-497},
number = {4},
note = {\doi{10.1016/j.cattod.2006.06.001}},
abstract = {This paper presents experimental and modelling results for the oxidation
of mixtures of hydrogen and carbon monoxide in a lean atmosphere.
{T}ransient light-off experiments over a platinum catalyst (80 g/ft^3
loading) supported on a washocated ceramic monolith were performed
with a slow inlet temperature ramp. {R}esults for {CO} alone agree
with earlier results that predict self-inhibition of {CO}; that is
an increasing light-off temperature with increasing {CO} concentration.
{A}ddition of hydrogen to the feed causes a reduction in light-off
temperature for all concentrations of {CO} studied. {T}he most significant
shift in light-off temperature occurs with the addition of small
amounts of hydrogen (500 ppm by volume) with only minor further enhancement
occurring at higher hydrogen concentrations. {H}ydrogen alone in
a lean atmosphere will oxidise at room temperature. {I}n mixtures
of hydrogen and {CO}, the {CO} was observed to react first until
a conversion of about 50% was observed, at which point the conversion
of hydrogen rapidly went from zero to 100%.
{S}imulations performed using literature mechanistic models for the
oxidation of these mixtures predicted that hydrogen ignites first,
followed by {CO}, a direct contradiction of the experimental evidence.
{U}pon changing the activation energy between adsorbed hydrogen and
oxygen, the {CO} was observed to oxidise first, however, no enhancement
of light-off was predicted. {T}he effect can not be explained by
the mechanistic model currently under discussion.},
doi = {10.1016/j.cattod.2006.06.001}
}
@ARTICLE{Salomons2004,
author = {S. Salomons and R. E. Hayes and M. Poirier and H. Sapoundjiev},
title = {Modelling a reverse flow reactor for the catalytic combustion of
fugitive methane emissions},
journal = {Computers \& {C}hemical {E}ngineering},
year = {2004},
volume = {28},
pages = {1599-1610},
number = {9},
note = {\doi{10.1016/j.compchemeng.2003.12.006}},
abstract = {This paper describes the development and validation of a computer
simulator for the modelling of a reverse flow catalytic reactor for
the combustion of lean mixtures of methane in air. {T}he simulator
uses a heterogeneous two dimensional model for the reactor. {T}he
reactor uses a packed bed for catalytic sections and ceramic monoliths
for inert sections, although the simulator is written in a general
fashion so that any combination of packing can be used, in any desired
variety. {V}alidation is performed using a 200 mm internal diameter
reactor over various flowrates and methane concentrations. {T}he
reverse flow reactor is observed to yield stable auto-thermal operation
even for low methane concentrations. {H}igher methane concentrations
are observed to give dual temperature peaks in the reactor. {T}he
transfer of energy is observed to be a significant factor in the
reactor operation, which is shown by comparison of the heterogeneous
model to a pseudo-homogeneous reactor model. {T}he simulator can
model the pilot reactor in real time for typical operating conditions.},
doi = {10.1016/j.compchemeng.2003.12.006},
keywords = {Catalytic combustion; Methane; Reverse flow},
language = {English}
}
@ARTICLE{Salomons2003a,
author = {S. Salomons and R.E. Hayes and M. Poirier and and H. Sapoundjiev},
title = {Flow reversal reactor for the catalytic combustion of lean methane
mixtures},
journal = {Catalysis {T}oday},
year = {2003},
volume = {83},
pages = {59-69},
number = {1-4},
note = {\doi{10.1016/S0920-5861(03)00216-5}},
abstract = {This paper describes an experimental investigation of a pilot scale
reverse flow reactor for the catalytic destruction of lean mixtures
of methane in air. {I}t was found that using reverse flow it was
possible maintain elevated reactor temperatures which were capable
of achieving high methane conversion of methane in air streams at
methane concentrations as low as 0.19% by volume. {T}he space velocity,
cycle time and feed concentration are all important parameters that
govern the operation of the reactor. {C}ontrol of these parameters
is important to prevent the trapping of the thermal energy within
the catalyst bed, which can limit the amount of energy that can be
usefully extracted from the reactor.},
doi = {10.1016/S0920-5861(03)00216-5},
keywords = {Catalytic combustion; Methane; Reverse flow},
language = {English}
}
@CONFERENCE{Sal2008,
author = {S. Salomons and R.E. Hayes and M. Votsmeier},
title = {The promotion of carbon monoxide oxidation by hydrogen on platinum},
booktitle = {5th International Conference on Environmental Catalysis},
year = {2008}
}
@CONFERENCE{Sal2006d,
author = {S. Salomons and R.E. Hayes and M. Votsmeier},
title = {On the {P}latinum {C}atalysed {O}xidation of {CO}/{H}$_{2}$ {M}ixtures
with and without {W}ater},
booktitle = {9th {C}anadian {S}ymposium on {C}atalysis},
year = {2006},
note = {9th Canadian Symposium on Catalysis},
abstract = {Automotive catalytic converters have been common for about thirty
years, and have been very effective in reducing pollution caused
by the automobile. {N}otwithstanding there evident success, there
remain many unanswered questions about the reactions that occur.
{F}or a three way catalyst, there is the oxidation of carbon monoxide
and hydrocarbons, as well as the reduction of oxides of nitrogen.
{F}or a lean oxidation catalyst, {N}o is typically oxidized to {NO}2.
{R}ecently, much attention has been paid to the use of computer aided
design methodologies for the improved design of catalytic devices.
{A}t the moment, most attention is devoted to lean oxidation catalysts,
because of the increasing emphasis on the use of diesel fuel.
{I}n modelling studies, two kinetic approaches have been used. {T}he
first uses global rate expressions based on {LHHW} type models, whilst
the second attempts to employ more mechanistically meaningful models.
{I}t is been shown that global models are able to predict some aspects
of converter performance but are incapable of modelling all observed
phenomena. {O}n the other hand, the common mechanistic models most
often cited in the catalytic converter literature have recently also
been shown to be unable to quantify all observed performance.
{T}he key reaction set for the oxidative catalytic converter can be
considered to be the system of carbon monoxide, hydrogen and water.
{W}ithout an understanding of this system, any attempt at a more
detailed mechanistic model must fail. {T}his paper deals with a systematic
study of this system in a real catalytic monolith with a washcoat
containing a platinum catalyst. {T}he experiments were transient
in nature, and include ignition and extinction curves, concentration
ramps and pulse responses. {T}he system was modelled using multi-step
mechanistic models using different hypotheses. {W}e present the predictive
ability of the common models from the converter literature, and highlight
their weaknesses. {N}ew steps are proposed that can explain some
of the observed behaviour.},
owner = {Salomons},
timestamp = {2006.03.06},
url = {http://www.engr.usask.ca/19csc2006/Keynote%20speakers.html}
}
@CONFERENCE{Sal2006b,
author = {Stephen Salomons and R.E. Hayes and Martin Votsmeier and Alfons Drocher
and Herbert Vogel and Jürgen Gieshoff},
title = {Oxidation of {CO}+{H}$_{2}$ on a {{P}t} {C}atalyst for the {R}eduction
of {D}iesel {E}xhaust {E}missions},
booktitle = {{{XXXIV}.} {J}ahrestreffen {D}eutscher {K}atalytiker 15.03. - 17.03.2006,
{W}eimar},
year = {2006},
abstract = {Much work has been done to understand and model the nature of the
reactions on a {P}t surface under diesel oxidation conditions. {T}he
oxidation of {CO} and hydrogen has been studied for the preferential
oxidation of {CO} in the production of clean hydrogen for use in
fuel cells, however less discussion has taken place on the reaction
under diesel exhaust gas conditions.
{T}ransient experiments (temperature ramps and concentration steps)
under lean conditions (0-2000 ppm {H}2, 0-2000 ppm {CO}, 6% {O}2,
rest {N}2, {SV} 25000 hr-1, atmospheric pressure, 25-300°{C}) are
presented and discussed. {S}imulations were performed using mechanistic
models from the literature and compared to experimental results.
{CO} is known to inhibit the oxidation of {H}2, whilst {H}2 promotes
the oxidation of {CO}. {T}his was experimentally verified, but in
addition, it was found that a small amount of hydrogen had a large
promotion effect, whereas the marginal effect of additional hydrogen
did not have a proportional effect. {T}his is shown in {F}igure 1,
where {CO} conversion is shown as the temperature of the reactor
is increased. {T}he addition of 500ppm {H}2 shows a large promotion
of the reaction. {T}he additional benefit of 2000ppm {H}2 is smaller.
{M}odels in the current literature do not accurately model this phenomenon,
and must be modified before agreement may be reached.
{E}xperimentally, the ignition of {CO} occurred before the ignition
of hydrogen during temperature ramp experiments. {S}imulations using
literature values were unable to predict the correct order of ignition.
{H}owever, when the activation energy for the reaction between adsorbed
hydrogen and oxygen be increased, the correct order of ignition was
obtained.},
file = {Sal2006b-Oxidation of CO+H2 on a Pt Catalyst for the Reduction of
Diesel Exhaust Emissions-Weimar39.pdf:Salomons\\Sal2006b-Oxidation
of CO+H2 on a Pt Catalyst for the Reduction of Diesel Exhaust Emissions-Weimar39.pdf:PDF},
owner = {Salomon}
}
@CONFERENCE{Hay2006,
author = {Robert Hayes and Rajab Litto and Joseph Mmbaga and Stephen Salomons
and Martin Votsmeier},
title = {Mechanistic {M}odelling of {M}ethane {C}ombustion on {P}alladium
in a {M}onolith {R}eactor},
booktitle = {11th {I}nternational {C}onference on {N}umerical {C}ombustion},
year = {2006},
month = {April},
organization = {Society for Industrial and Applied Mathematics},
note = {11th International Conference on Numerical Combustion
April 23-26, 2006
Granada , Spain},
owner = {Salomons},
timestamp = {2006.03.02},
url = {http://meetings.siam.org/sess/dsp_programsess.cfm?SESSIONCODE=5573}
}
@CONFERENCE{Salomons2005,
author = {Stephen Salomons and Alfons Drochner and Herbert Vogel and Martin
Votsmeier and Jürgen Gieshoff and R.E. Hayes},
title = {Validation of {CO} oxidation models for a {M}onolith-based {{P}t}
{D}iesel {O}xidation {C}atalyst},
booktitle = {{{XXXVIII}.} {J}ahrestreffen {D}eutscher {K}atalytiker 16.03. - 18.03.2005,
{W}eimar},
year = {2005},
month = {March},
note = {{XXXVIII.} {J}ahrestreffen {D}eutscher {K}atalytiker 16.03. - 18.03.2005,
{W}eimar},
abstract = {There is a need for a {CO}-oxidation model for a {P}t-based {D}iesel
{O}xidation {M}onolith {C}atalyst that is valid over a range of transient
conditions. {S}uch a model would assist in both simulations of catalyst
performance and in optimizing the performance of a catalyst via an
on-boad computer. {T}he objective of this work was to validate experimentally
some {CO} oxidation reaction mechanisms currently used in modelling
platinum-based diesel oxidation monolith catalysts. {M}any steady-state
and transient measurements of catalytic activity using {C}oncentration
{P}rogrammed {M}ethods ({CO} ramps and step-functions) and {T}emperature
{P}rogrammed {M}ethods (lightoff and extinction curves) were made
over the typical operating conditions of a diesel oxidation monolith
catalyst (atmospheric pressure, 50-300 °{C}). {V}arious mixtures
of {N}2, {O}2, {CO}2, {CO} and {H}2{O} were used. {T}hese experiments
were compared to numerical solutions of published mechanisms. {T}he
reactor simulator was developed by {M}ukadi and {H}ayes [1]. {A}
generalized pattern search ({GPS}) algorithm was used for parameter
estimation. {S}trengths and weaknesses of the various models are
discussed and compared. {T}he mechanisms for modelling {CO} oxidation
on {P}t used in this work were based on elementary reactions [2,3]
and a global reaction mechanism [4]. {N}one of the three mechanisms
perfectly describes all experimental results over the full operating
range, especially under transient conditions. {S}ome evidence is
found that the prolonged operation of the catalyst under reactive
conditions leads to a reversible decrease in performance. {T}his
effect is often attributed to sub-surface oxidation of the platinum,
and so far this effect is not taken into account in the mechanisms
applied for modelling of diesel oxidation catalysts.},
file = {2005-Weimar-poster-2.pdf:Salomons\\2005-Weimar-poster-2.pdf:PDF},
owner = {Stephen},
url = {http://events.dechema.de/Posterprogramm-page-12528.html}
}
@CONFERENCE{Salomons2005a,
author = {Stephen Salomons and Alfons Drochner and Herbert Vogel and Martin
Votsmeier and Stephan Malmberg and Jürgen Gieshoff and R.E. Hayes},
title = {Validation of {CO} oxidation models for a {{P}t} diesel oxidation
catalyst},
booktitle = {4th {I}nternational {C}onference on {E}nvironmental {C}atalysis,
{H}eidelberg, {G}ermany},
year = {2005},
month = {June},
note = {4th International Conference on Environmental Catalysis \url{http://ssalomons.fastmail.fm/200506-Salomons_et_al-Heidelberg_ICEC4_poster-CO_oxidation_models.pdf}},
abstract = {The oxidation of {CO} has been studied for many years both because
it is an interesting reaction in its own right, as well as being
an important reaction for automotive catalytic converters. {T}he
objective of this work was to validate experimentally some {CO} oxidation
reaction mechanisms currently used in modelling platinum diesel oxidation
catalysts. {M}any steady-state and transient measurements of catalytic
activity involving {CO} ramps, step-functions and light-offs were
made over the typical operating conditions of a diesel oxidation
catalyst (atmospheric pressure, 50-300°{C}, with and without water).
{T}hese experiments were compared to numerical solutions of published
mechanisms using the reactor simulator developed by {M}ukadi and
{H}ayes [1], coupled with a generalized pattern search ({GPS}) algorithm
for parameter estimation. {S}trengths and weaknesses of the various
models are discussed and compared. {T}he mechanisms for modelling
{CO} oxidation on {P}t used in this work were based on elementary
reactions [2,3] and a global reaction mechanism [4]. {N}one of the
three mechanisms perfectly describes all experimental results over
the full operating range, especially under transient conditions.
{S}ome evidence is found that the prolonged operation of the catalyst
under reactive conditions leads to a reversible decrease in performance.
{T}his effect is often attributed to sub-surface oxidation of the
platinum, and so far this effect is not taken into account in the
mechanisms applied for modelling of diesel oxidation catalysts.},
comment = {http://ssalomons.fastmail.fm/200506-Salomons_et_al-Heidelberg-CO_oxidation_models.pdf},
file = {200506-Heidelberg-Abgas.A4.pdf:Salomons\\200506-Heidelberg-Abgas.A4.pdf:PDF},
owner = {Stephen},
url = {http://events.dechema.de/data/tagungen_/Geiling/ICEC_Internet_PosterProgr.pdf}
}
@CONFERENCE{Salomons2005c,
author = {Stephen Salomons and R.E. Hayes and Alfons Drochner and Herbert Vogel
and Martin Votsmeier and Jürgen Gieshoff},
title = {Validation of {{CO}+{H}\(_{2}\)} {O}xidation {M}odels for a {{P}t}-based
{M}onolith {D}iesel {O}xidation {C}atalyst},
booktitle = {6th {I}nternational {W}orkshop on {C}atalytic {C}ombustion, {I}schia,
{I}taly},
year = {2005},
month = {September},
organization = {6th International Workshop on Catalytic Combustion (IWCC 6)},
note = {6th International Workshop on Catalytic Combustion (IWCC 6)},
abstract = {As emission standards become more and more rigorous, the need for
more efficient and effective catalytic converters and more detailed
knowledge of the diesel automotive catalyst increases. {W}hile the
oxidation of {CO} has been thoroughly studied, little is known about
the combination of {CO}+{H}2, especially under lean conditions in
a {P}t-based monolith diesel oxidation catalyst. {C}urrently, no
published model accurately accounts for all phenomena in this system.
{A}n accurate model of this system would assist not only in the development
of better on-board emission control systems for automobiles, but
would also facilitate more effective design of new catalytic converters.
{T}he objective of this work was to experimentally validate some
{CO}+{H}2 oxidation reaction mechanisms currently used in modelling
platinum diesel oxidation catalysts. {T}he mechanisms were first
studied for {CO} oxidation alone, then for {H}2 alone, and then both
in combination. {B}y studying {CO} and {H}2 both alone and in combination,
the effect of {H}2 on {CO} oxidation, and the effect of {CO} on {H}2
oxidation, has been observed. {I}t is known that {CO} inhibits the
ignition of {H}2, and {H}2 promotes the ignition of {CO} [1], however
the interactions between kinetics, mass and energy transfer in a
monolith are not well understood, especially under transient conditions.
{T}he presence of phenomena such as moving ignition and extinction
fronts are difficult to accurately model. {A}s the complexity of
the system increases, the robustness of the models may be studied.
{M}any steady-state and transient measurements of catalytic activity
involving concentration ramps, step-functions and lightoffs were
made over the typical operating conditions of a diesel oxidation
catalyst (atmospheric pressure, 50-300 °{C}, with and without water).
{T}hese experiments were compared to numerical solutions of published
mechanisms using the reactor simulator developed by {M}ukadi and
{H}ayes [2]. {S}trengths and weaknesses of the various models are
discussed and compared. {T}he mechanisms for modelling {CO}+{H}2
oxidation on {P}t used in this work were based on elementary reactions
[3, 4]. {N}either of the mechanisms perfectly describes all experimental
results over the full operating range, especially under transient
conditions. {R}eferences [1] {M}ingyong {S}un, {E}ric {B}. {C}roiset,
{R}obert {R}. {H}udgins, {P}eter {L}. {S}ilveston, and {M}ichael
{M}enzinger. {S}teady-state multiplicity and superadiabatic extinction
waves in the oxidation of {CO}/{H}2 mixtures over a {P}t/{A}l2{O}3-coated
monolith. {I}ndustrial & {E}ngineering {C}hemistry {R}esearch, 42(1):37-45,
2003. [2] {L}.{S}. {M}ukadi and {R}.{E}. {H}ayes. {M}odelling the
three-way catalytic converter with mechanistic kinetics using the
{N}ewton-{K}rylov method on a parallel computer. {C}omputers and
{C}hemical {E}ngineering, 26(3):439-455, 2002. [3] {J}.{H}.{B}.{J}.
{H}oebink, {J}.{M}.{A}. {H}armsen, {M}. {B}alenovic, {A}.{C}.{P}.{M}.
{B}ackx, and {J}.{C}. {S}chouten. {A}utomotive exhaust gas conversion:
from elementary step kinetics to prediction of emission dynamics.
{C}atalysis {T}oday, 16/17(1-4):319-327, 2001. [4] {D}aniel {C}hatterjee,
{O}laf {D}eutschmann, and {J}ürgen {W}arnatz. {D}etailed surface
reaction mechanism in a three-way catalyst. {F}araday {D}iscussions,
119:371-384, 2001.},
comment = {Tuesday 13 September 2005, 1000},
file = {Salomons2005c-IWCC6-Italy200509-Validation of CO+H2 Oxidation Models
for a Pt based Monolith Diesel Oxidation Catalyst.ppt:Salomons\\Salomons2005c-IWCC6-Italy200509-Validation
of CO+H2 Oxidation Models for a Pt based Monolith Diesel Oxidation
Catalyst.ppt:PDF},
owner = {Stephen},
url = {http://www.iwcc6.unisa.it/programmeIWCC6.doc}
}
@CONFERENCE{Salomons2002,
author = {Salomons, S. and Hayes, R.E. and Poirier, M. and Sapoundjiev, H.},
title = {The catalytic combustion of lean methane mixtures using a reverse
flow reactor},
booktitle = {C{SC}2002 {V}ancouver},
year = {2002},
month = {June},
note = {CSC2002 Vancouver CA2 IRC 1 Environmental Catalysis 13:20 00487},
file = {00000954.htm:Salomons\\CSC2002\\00000954.htm:PDF},
owner = {Stephen},
url = {http://csc2002.chemistry.ca/program/00000954.htm}
}
@CONFERENCE{Poi2002,
author = {Poirier, M.G. and Sapoundjiev, H. and Salomons, S. and Hayes, R.E.},
title = {Pressure drop reduction by using monolith in a pilot-scale flow reversal
reactor},
booktitle = {C{SC}2002 {V}ancouver},
year = {2002},
month = {June},
note = {CSC2002 Vancouver CA2 IRC 1 Environmental Catalysis 14:20 00490},
file = {00001047.htm:Salomons\\CSC2002\\00001047.htm:PDF},
owner = {Stephen},
url = {http://csc2002.chemistry.ca/program/00001047.htm}
}
This file has been generated by bibtex2html 1.88.